Search results for "stable isotope"
showing 10 items of 437 documents
Estimating ion confinement times from beam current transients in conventional and charge breeder ECRIS
2019
International audience; Cumulative ion confinement times are probed by measuring decaying ion current transients in pulsed material injection mode. The method is applied in a charge breeder and conventional ECRIS yielding mutually corroborative results. The cumulative confinement time estimates vary from approximately 2 ms–60 ms with a clear dependence on the ion charge-to-mass ratio—higher charges having longer residence times. The long cumulative confinement times are proposed as a partial explanation to recently observed unexpectedly high ion temperatures. The results are relevant for rare ion beam (RIB) production as the confinement time and the lifetime of stable isotopes can be used f…
Diagenetic stability of non-traditional stable isotope systems (Ca, Sr, Mg, Zn) in teeth – An in-vitro alteration experiment of biogenic apatite in i…
2021
Stable isotope ratios and trace element concentrations of fossil bones and teeth are important geochemical proxies for the reconstruction of diet and past environment in archaeology and palaeontology. However, since diagenesis can significantly alter primary diet-related isotope signatures and elemental compositions, it is important to understand and quantify alteration processes. Here, we present the results of in-vitro alteration experiments of dental tissues from a modern African elephant molar reacted in aqueous solutions at 30 °C and 90 °C for 4 to 63 days. Dental cubes with ≈ 3 mm edge length, comprising both enamel and dentin, were placed into 2 mL of acidic aqueous sol…
Environmental and biological factors are joint drivers of mercury biomagnification in subarctic lake food webs along a climate and productivity gradi…
2021
Subarctic lakes are getting warmer and more productive due to the joint effects of climate change and intensive land-use practices (e.g. forest clear-cutting and peatland ditching), processes that potentially increase leaching of peat- and soil-stored mercury into lake ecosystems. We sampled biotic communities from primary producers (algae) to top consumers (piscivorous fish), in 19 subarctic lakes situated on a latitudinal (69.0-66.5 degrees N), climatic (+3.2 degrees C temperature and +30% precipitation from north to south) and catchment land-use (pristine to intensive forestry areas) gradient. We first tested how the joint effects of climate and productivity influence mercury biomagnific…
Soil development on sediments and evaporites of the Messinian crisis
2020
Abstract Vast areas in the Mediterranean are characterised by evaporite deposits of the Messinian crises (c. 6–5.3 Ma BP). During this period, large deposits were built up in shallow lagoon-like systems and are now found in southern Italy, Albania, Cyprus and Turkey. So far, soil formation on evaporites has been studied predominantly in subarid to arid environments. Although the formation of soils has received new significance, little is known about the evolutional trajectories on evaporites of the Mediterranean. We therefore studied soil formation in the Caltanissetta basin (Sicily) where evaporites are most widespread. The lithologies included the sequence: marine clay deposits, laminated…
Intra- and inter-annual uranium concentration variability in a Belizean stalagmite controlled by prior aragonite precipitation: A new tool for recons…
2016
Aragonitic speleothems are increasingly utilised as palaeoclimate archives due to their amenability to high precision U–Th dating. Proxy records from fast-growing aragonitic stalagmites, precisely dated to annual timescales, can allow investigation of climatic events occurring on annual or even sub-annual timescales with minimal chronological uncertainty. However, the behaviour of many trace elements, such as uranium, in aragonitic speleothems has not thus far been as well constrained as in calcitic speleothems. Here, we use uranium concentration shifts measured across primary calcite-to-aragonite mineralogical transitions in speleothems to calculate the distribution coefficient of uranium …
Petrographic and geochemical characterization of the Middle‒Upper Jurassic Fe–Mn crusts and mineralizations from Monte Inici (north-western Sicily): …
2021
AbstractFe–Mn concretions and mineralizations, associated with condensed horizons and hardground, are significant archives in ancient carbonate rocks. Their petro-chemical study allows an assessment of the palaeoenvironmental context in which they were formed also connected to their biotic or abiotic origin. At the western side of the Monte Inici (Fornazzo section, north-western Sicily) a well exposed outcrop of condensed pelagic limestones (Rosso Ammonitico facies: Middle‒Upper Jurassic) is well-known and thoroughly studied. In this section, the base of the Rosso Ammonitico facies consists of a very condensed level rich in fossils with a variable thickness deposited from the early Bathonia…
Integrated biomonitoring of airborne pollutants over space and time using tree rings, bark, leaves and epiphytic lichens
2016
The integrated use of tree rings and outer tissues, and lichens, was tested for monitoring how pollutant concentrations vary in space and over time nearby an incinerator in industrial area in Central Italy. Trace elements in thalli of lichen Xanthoria parietina and in leaves, bark, wood of Quercus pubescens, as well as carbon, oxygen and nitrogen isotope ratios in tree rings were analyzed. Some trace elements in the leaves differed significantly between the plots, though this was not the case in lichens and bark. The values of δ13C and δ18O showed the same trend in all plots, while the values of δ15N were higher in the distal plot. The results indicated that trace elements were intercepted …
Geodynamic control on carbonate diagenesis: Petrographic and isotopic investigation of the Upper Jurassic formations of the Paris Basin (France).
2007
23 pages; International audience; The Oxfordian and Kimmeridgian carbonates of the eastern edge of the Paris Basin display poor reservoir properties (Φb15% and Kb0.1 md). The petrographic investigation and the resultant paragenetic sequence show that this is due to extensive precipitation of 2 types of almost synchronous blocky LMC (Low Magnesian Calcite) cements during mesogenesis (burial). Stable isotope investigation of these non-recrystallized cements, through both microdrilling sampling and in-situ SIMS (Secondary IonMass Spectrometry) analysis, shows that they originated from slightly buffered meteoric fluids (−3‰SMOW to −8‰SMOW) flowing through the Malm carbonate aquifers of the east…
13C composition of dissolved organic carbon in upland forested catchments of the Morvan Mountains (France): Influence of coniferous and deciduous veg…
2007
10 pages; International audience; One of the main environmental changes caused by human activities is that of land use. These changes influence the quantity and quality of the dissolved organic matter (DOM) fluxes through the vegetation–soil–stream system. The aim of this work is to evaluate the influence of the substitution of native deciduous forests by well managed coniferous forests on dissolved organic carbon (DOC) fluxes and their associated carbon isotopic composition (d13CDOC). DOC fluxes and d13CDOC were monitored for 2 years in the streams of four similar upland forested catchments in the Morvan Mountains (France). Mean annual DOC concentrations and fluxes were 2–4 times lower in …
Identification of processes that control the stable isotope composition of rainwater in the humid tropical West-Central Africa.
2020
12 pages; International audience; This study interprets 11 years (2006 to 2016) and 6 months (March to August in 2017) of respectively monthly and daily isotopic (δD and δ18O) monitoring of rain at Douala (Cameroon), a humid tropical station in Western Africa. The main scope is to analyze the climate controls on precipitation isotopes at different timescales. Firstly, we examine the annual cycles of δ18O. Over the 11 years of survey, the annual cycle exhibits a W shape that is quite reproducible from year to year, with two minima in spring and autumn periods. Based on back trajectory calculations and remote sensing observations of water vapor isotopic composition, we show that the observed …